Probing alkenoxy radical electronic structure using anion PEI spectroscopy
نویسندگان
چکیده
منابع مشابه
Probing the connection between cluster and bulk electronic structure of InP using vacuum ultraviolet anion photoelectron spectroscopy
Vacuum ultraviolet photoelectron (PE) spectra of InxP x ðx 1⁄4 2–13Þ clusters were measured to probe the evolution of their electronic structure with size. The spectra of smaller (x6 6) clusters show numerous discrete electronic features, with fewer seen for x 1⁄4 7 and 8. For xP 9, the PE spectra comprise two broad peaks resembling the first two valence bands of the InP bulk photoemission spec...
متن کاملProbing the electronic structure of [MoOS(4)](-) centers using anionic photoelectron spectroscopy.
Using photodetachment photoelectron spectroscopy (PES) in the gas phase, we investigated the electronic structure and chemical bonding of six anionic [Mo(V)O](3+) complexes, [MoOX(4)](-) (where X = Cl (1), SPh (2), and SPh-p-Cl (3)), [MoO(edt)(2)](-) (4), [MoO(bdt)(2)](-) (5), and [MoO(bdtCl(2))(2)](-) (6) (where edt = ethane-1,2-dithiolate, bdt = benzene-1,2-dithiolate, and bdtCl(2) = 3,6-dich...
متن کاملProbing the electronic structure of peptide bonds using methyl groups.
The observed V3 torsional barriers measured by microwave spectroscopy for nine methyl groups attached alpha to peptide bond linkages in five gas-phase biomimetics have been found to differ considerably from one molecule to the next and even depend on the position of substitution, being sensitive to structural changes at the other end of the peptide bond. In the search for an explanation for the...
متن کاملSpectroscopy and dynamics of the 7,7,8,8-tetracyanoquinodimethane radical anion.
The photoelectron spectrum of the 7,7,8,8-tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (1(2)B(3u)) of TCNQ(-) have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state ((2)B(2g)) with an associated lifetime ...
متن کاملElectronic structure of indium phosphide clusters: anion
Ž . Photoelectron spectra for indium phosphide InP cluster anions comprised of up to 27 atoms were measured at a photodetachment wavelength of 266 nm. Results are presented for cluster anions of both stoichiometric and non-stoichiometŽ y y . Ž . ric composition In P , In P ; xs1–13 . In P exhibits the lowest electron affinity EA of all the clusters studied, x x xq1 x 3 3 indicating a particular...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2019
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.5064795